Faculty Information - HASHIMOTO KAZUAKI

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Academic background

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Research activities

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（Last updated : 2026-02-23 17:27:13）

HASHIMOTO KAZUAKI
Department of Applied Chemistry, Faculty of Engineering

Graduate School of Engineering

Master's Program in Applied Chemistry, Graduate School of Engineering

Professor

■ Office

Tsudanuma Campus, No.1 Building,3rd floor room 020307

■ Academic background

1989/04～1992/03

〔Doctorial Course〕 Department of Industrial Chemistry, Faculty of Engineering,, Chiba Institute of Technology, Completed, Ph.D in Inorganic Industrial Chemistry

■ Present specialized field

Inorganic materials and properties, Structural materials and functional materials, Biomedical engineering, Inorganic compounds and inorganic materials chemistry (Key Word：Industrial Inorganic Chemistry,Ceramic Material Science)

■ E-Mail Address

■ Research activities

1.	2010/06～2025/06	∟ Councilor
2.		Japan Society Colour Material
3.	2016/03～2019/07	∟ Chairperson
4.		AcerS
5.		ACS

■ Works

1.	Book	Nanobioceramics for Healthcare Applications pp.79-104 (Collaboration) 2017/04
2.	Article	Fabricating ordered porous β-tricalcium phosphate ceramics having specific structure via the replica method using 3D-CAD-designed polymeric templates Open Ceramics 25,pp.100928 (Collaboration) 2026/02/14
3.	Article	Electrostatic layer-by-layer assembly for fabricating morphology-controlled hydroxyapatite/zirconia composite with enhanced osteogenic performance Bio-Medical Materials and Engineering 2026 (Collaboration) 2026/02/12
4.	Article	EFFECTS OF TRIVALENT AND PENTAVALENT VANADIUM SUBSTITUTION ON THE SINTERING CHARACTERISTICS AND MICROSTRUCTURE OF β-TRICALCIUM PHOSPHATE CERAMICS Phosphorus Research Bulletin 42,pp.16-23 (Collaboration) 2025/12/25
5.	Article	Evaluation of Composites Comprising Spherical, Porous, Sintered β-Tricalcium Phosphate Particles and Cyanoacrylate as Bone Cement Journal of Functional Biomaterials 16(12),pp.458 (Collaboration) 2025/12/09
6.	Article	Special Issue “Bioceramics: Challenges andMedical Applications of Calcium-Phosphate-Based Biocompatible Ceramics” International Journal of Molecular Sciences 26,pp.10612 (Collaboration) 2025/10/31
7.	Article	Characterization and confirmation of the long lifetime of a-decade-aged hydroxyapatite ceramic electrets. Scientific Reports 15,pp.9660 (Collaboration) 2025/03/20
8.	Article	Exploring the Biological Impact ofβ-TCP Surface Polarization on Osteoblast and Osteoclast Activity, International Journal of Molecular Science 26(1),pp.141 (Collaboration) 2024/12/27
9.	Article	Enhanced Sinterability and Mechanical Strength of Beta-type Tricalcium Phosphates Ceramics through Reaction Sintering with Hydroxyapatite. Journal of the European Ceramic Society 45(4),pp.117023 (Collaboration) 2024/10/25
10.	Article	Characterization of porous β-tricalcium phosphate fabricated by physical foaming with a nonionic surfactant: Effect of adding a thickener, Journal of Ceramic Society of Japan 132(6),pp.275-279 (Collaboration) 2024/06/01
11.	Article	Characterization of Porous β-Type Tricalcium Phosphate Ceramics Formed via Physical Foaming with Freeze-Drying, International Journal of Molecular Science 25,pp.5363 (Collaboration) 2024/05/14
12.	Article	Effect of Silicon Dioxide Nanoparticles on the Sintering Properties of Beta-Tricalcium Phosphate Composites, Materials 17,pp.797 (Collaboration) 2024/02/07
13.	Article	PREPARATION OF SILICON-SUBSTITUTED BETA-TRICALCIUM PHOSPHATE BY THE POLYMERIZED COMPLEX METHOD Phosphorus Research Bulletin 39,pp.14-22 (Collaboration) 2023/07
14.	Article	Crystal growth of HAp on plate-like ZnO particles using APTES as surface treatment agents JOUNAL OF ASIAN CERAMIC SOCIETIES 11(1),pp.https://doi.org/10.1080/21870764.2022.2148386 (Collaboration) 2023/03/09
15.	Article	Preparation and photocatalytic activity of shape controlled zinc oxide particles using anionic surfactant as a crystal-growth-directing agent Acc. Mater. Surf. Res. pp.103-111 (Collaboration) 2022/08
16.	Article	Electrical polarization and ionic conduction properties of β-tricalcium phosphate ceramics with controlled vacancies by sodium ion substitution Ceramics International 48(11),pp.15791-15799 (Collaboration) 2022/06
17.	Article	Preparation and Photocatalytic Activity of Hexagonal Plate-like ZnO Particles Using Anionic Surfactants Journal of Oleo Science 71(6),pp.927-932 (Collaboration) 2022/06
18.	Article	Synthesis and Photocatalytic Activity of Hexagonal Plate-like Shaped Au Nanoparticles/ZnO Composite Particles under Visible-light Irradiation Journal of Oleo Science 71(5),pp.771-778 (Collaboration) 2022/05
19.	Article	PREPARATION OF POROUS β-TRICALCUM PHOSPHATE BY FOAMING METHOD USING CELLULOSE NANOFIBERS WITH DIFFERENT MANUFACTURING METHODS AS FOAM STABILIZER Phosphorus Research Bulletin 38,pp.032-036 (Collaboration) 2022/04
20.	Article	Fabrication and characterization of beta-type tricalcium phosphate sintered body with phosphorus/sulphur-complex cations Journal of the Ceramic Society of Japan 130(1),pp.88-93 (Collaboration) 2022/01
21.	Article	FABRICATION OF POROUS β-TRICALCIUM PHOSPHATE SCAFFOLDS USING FOAM REPLICA WITH 3D TECHNOLOGY Phosphorus Research Bulletin 37,pp.32-38 (Collaboration) 2021/12
22.	Article	Effect of Anionic Amphiphiles on the Morphology of Hexagonal Plate-like ZnO Particle Journal of Oleo Science 70(7),pp.919-925 (Collaboration) 2021/07
23.	Article	The Effect of UV Light Irradiation on Fibroblast on Titania/Silica Composite Film Modified with Silane Coupling Agent 材料技術 38(5),pp.97-103 (Collaboration) 2020/09
24.	Article	Preparation of Hexagonal Plate-like ZnO Single-crystal Particles in the Presence of Anionic Amphiphiles Journal of Oleo Science 69(7),pp.783-787 (Collaboration) 2020/07
25.	Article	非イオン性界面活性剤により修飾されたポリカーボネート基板上におけるリン酸カルシウム粒子の調製材料技術 38(2),pp.35-39 (Collaboration) 2020/04
26.	Article	Immobilization of DNA on Quartz Crystal Microbalance Sensor Modified with Self-Assembled　Monolayer of Thiol Derivative Journal of Oleo Science 69(3),pp.271-276 (Collaboration) 2020/03
27.	Article	Size Control Synthesis of Hydroxyapatite Plates and Their Application in the Preparation of Highly Oriented Films Crystal Growth & Design. 18(9),pp.5038-5044 (Collaboration) 2018
28.	Article	Morphological and functional changes in RAW264 macrophage-like cells in response to a hydrated layer of carbonate-substituted hydroxyapatite Journal of Biomedical Materials Research Part A 105(4),pp.1063-1070 (Collaboration) 2017/04
29.	Article	A critical phenomenon of phase transition in hydroxyapatite investigated by thermally stimulated depolarization currents Journal of the American Ceramic Society 100(2),pp.501-505 (Collaboration) 2017/02
30.	Article	Crystallization of Calcium Phosphate in Agar Hydrogels in the Presence of Polyacrylic Acid under Double Diffusion Conditions Crystal Growth & Design 17(2),pp.604-611 (Collaboration) 2017/02
31.	Article	History of the Use of Inorganic Pigment pp.27-31 (Single) 2017/01
32.	Article	Creation of giant two-dimensional crystal of zinc oxide nanodisk by method of single-particle layer of organo-modified inorganic fine particles 453,pp.90-99 (Collaboration) 2015/09
33.	Article	Fibroblast cell proliferation on photo-cured terhalose cinnamoyl ester thin films Journal of Bioactive and Compatible Polymers 30(1),pp.87-98 (Collaboration) 2015/01
34.	Article	Fabrication and BSA Adsorption/Desorption Properties of Titania/Silica Composite Films Modified with Silane Coupling Agents Journal of Oleo Science 63(10),pp.1077-1083 (Collaboration) 2014/10
35.	Article	Formation and Structure of Single Particle Layer Induced to Construction of New Type Two-dimensional Organic / Inorganic Nanohybrids Transactions of the Materials Research Society of Japan 39(1),pp.91-94 (Collaboration) 2014/01
36.	Article	Evaluation of Grinding Characteristics of Calcium Carbonate Using High-Flow Recirculation Bead Mill Journal of the Society of Inorganic Materials, Japan 20(363),pp.76-83 (Collaboration) 2013/03
37.	Article	Influence of Bead Diameter on the Grinding Efficiency of a High-Flow Recirculation Bead Mill Journal of the Society of Inorganic Materials, Japan 20(362),pp.41-49 (Collaboration) 2013/01
38.	Article	Effect of Polarization Treatment Time on Inhibition of Low Temperature Degradation in Y-Doped ZrO2 Key Engineering Materials 529-530,pp.601-603 (Collaboration) 2013
39.	Article	Dispersibility Evaluation of Carbon Nanotubes Using Bead Mill Journal of the Japan Society of Colour Material 85(9),pp.357-364 (Collaboration) 2012/09
40.	Article	EVALUATION OF THE CELL CYTOTOXICITY OF β-TRICALCIUM PHOSPHATE DOPED WITH VANADIUM IONS Phosphorus Research Bulletin 26,pp.113-116 (Collaboration) 2012/07
41.	Article	Proliferation and differentiation of osteoblast-like cells on beta-tricalium phosphate doped with manganese(II) ions Phosphorus Research Bulletin 26,pp.87-90 (Collaboration) 2012/07
42.	Article	Sintering and Osteoclast Behavior of Carbonate Apatite Ceramics Phosphorus Research Bulletin 27,pp.45-49 (Collaboration) 2012/07
43.	Article	Polarized Yttria-Stabilized Zirconia Improves Durability for Degradation and Apatite Formation in Simulated Body Fluid Phosphorus Research Bulletin 26,pp.77-80 (Collaboration) 2012/06
44.	Article	Endothelial cell migration and morphogenesis on silk fibroin scaffolds containing hydroxyapatite electret Journal of Biomedical Materials Research Part A 100A(4),pp.969-977 (Collaboration) 2012/04
45.	Article	Electric polarization and mechanism of B-type carbonated apatite ceramics Journal of Biomedical Materials Research Part A 99A(1),pp.116-224 (Collaboration) 2011/01
46.	Article	Improving bioactivity and durability of yttria-stabilized zirconia JOURNAL OF MATERIALS SCIENCE 46(22),pp.7335-7343 (Collaboration) 2011
47.	Article	Preparation and Photocatalytic Activity under Visible Light Irradiation of Mesostructured Titania Particles Modified with Phthalocyanine in the Pores Journal of Photochemistry and Photobiology A: Chemistry 217(1),pp.136-140 (Collaboration) 2011
48.	Article	Synthesis of Spherical Calcium Phosphate using Gas/Liquid Interface as Templates Material Technology 29,pp.210-217 (Collaboration) 2011
49.	Article	Fast oxide ion conduction due to carbonate substitution in hydroxyapatite Journal of the American Ceramic Society 93(11),pp.3577-3579 (Collaboration) 2010/11
50.	Article	Preparation of Beta-Tricalcium Phosphate Powder Substituted with Na/Mg Ions by Polymerized Complex Method Journal of the American Ceramic Society 93(11),pp.3663-3670 (Collaboration) 2010/11
51.	Article	Biocompatibility and water durability of alumina-zirconia ceramics blended with microsized HA particles Journal of the Ceramic Society of Japan 118(1378),pp.498-501 (Collaboration) 2010
52.	Article	Dissolution mechanisms of β-tricalcium phosphate doped with monovalent metal ions Journal of the Ceramic Society of Japan 118(1378),pp.451-457 (Collaboration) 2010
53.	Article	Mechanical Properties of Beta-tricalcium Phosphate Ceramics doped with Vanadate ions Phosphorus Research Bulletin 24,pp.73-78 (Collaboration) 2010
54.	Article	Surface Electric Fields Increase Osteoblast Adhesion through Improved Wettability on Hydroxyapatite Electret ACS Appl. Mater. Interfaces 1(10),pp.2181-2189 (Collaboration) 2009/10
55.	Article	Thermal stability of Beta-tricalcium phosphate doped with monovalent metal ions Materials Research Bulletin 44(9),pp.1889-1894 (Collaboration) 2009/09
56.	Article	Preparation and characterization of beta-tricalcium phosphate co-doped with monovalent and divalent antibacterial metals ions Acta Biomaterialia 5(8),pp.3157-3164 (Collaboration) 2009/08
57.	Article	Preparation of beta-Tricalcium Phosphate by Chelate Reaction of Calcium Ion with Phosphonic Acid Transactions of the Materials Research Society of Japan 34(1),pp.81-84 (Collaboration) 2009/01
58.	Article	Cellular evaluation of C7 cells on Mn²⁺ ion-doped beta-tricalcium phosphate ceramics Archives of BioCeramics Research 9,pp.375-378 (Collaboration) 2009
59.	Article	Cellular evaluation of MC3T3-E1 cells on VO₄^3- ions-doped beta-tricalcium phosphate ceramics Archives of BioCeramics Research 9,pp.299-302 (Collaboration) 2009
60.	Article	ST2/C7 cells behavior on bioelectronic ions co-doped beta-tricalcium phosphate ceramics Archives of BioCeramics Research 9,pp.291-294 (Collaboration) 2009
61.	Article	Surface Electric Fields Increase Osteoblast Adhesion through Improved Wettability on Hydroxyapatite Electret ACS Appl. Mater. Interfaces 1(10),pp.2181-219 (Collaboration) 2009
62.	Article	Synthesis and characterization of hydroxyapatite using polymerized complex method by chelation of calcium ions with organic phosphonic acid Journal of the Ceramic Society of Japan 117(1363),pp.249-254 (Collaboration) 2009
63.	Article	Rate of Bonelike Apatite Formation Accelerated on Polarized Porous Hydroxyapatite Journal of the American Ceramic Society 91(12),pp.3943-3949 (Collaboration) 2008/12
64.	Article	The Color Shift of Cerium Molybdenum Sheelite by Substituting Bi³⁺ or W⁶⁺ Ion Journal of Japan Society of Colour Material(Shikizai Kyokaishi) 81(2),pp.73-79 (Collaboration) 2008/02
65.	Article	Rate of Bonelike Apatite Formation Accelerated on Polarized Porous Hydroxyapatite Journal of American Ceramics Society 91(12),pp.3943-3949 (Collaboration) 2008
66.	Article	Reaction sintering of two-dimensional silicon carbide fiber-reinforced silicon carbide composite by sheet stacking method Journal of Nuckear Materials 367-370,pp.769-773 (Collaboration) 2008
67.	Article	Reaction sintering of beta-tricalcium phosphates and their mechanical properties Journal of the European Ceramic Society 27(10),pp.3215-3220 (Collaboration) 2007/10
68.	Article	Improvement of the external quantum efficiency of lithium europium tungstate and its application to white light emitting diodes Journal of Japan Society of Colour Material (Shikizai Kyokaishi) 80(6),pp.246-252 (Collaboration) 2007/06
69.	Article	Preparation and antibacterial evaluation of two-layered aluminum anodic oxide film electrodeposited titanium dioxide Journal of Japan Institute of Light Metals (keikizoku) 57(4),pp.146-151 (Collaboration) 2007/04
70.	Article	Preparation and optical property of titanium dioxide flake as a novel iridescent material Journal of Japan Society of Colour Material(Shikizai Kyokaishi) 80(3),pp.107-115 (Collaboration) 2007/03
71.	Article	Fabrication of Two Dimensional Silicon Carbide Fiber-Reinforced Silicon Carbide Composite by Electrophoretic Deposition and Hot-Pressing Key Engineering Materials 352,pp.77-80 (Collaboration) 2007
72.	Article	Reaction sintering of two-dimensional silicon carbide fiber-reinforced silicon carbide composite by sheet stacking method Journal of Nuclear Materials 367-370,pp.769-773 (Collaboration) 2007
73.	Article	Preparation and optical properties of titanium dioxide iridescent pigment based on black titanium oxynitride Journal of Japan Society of Colour Material (Shizai Kyokaishi) 79(12),pp.526-534 (Collaboration) 2006/12
74.	Article	Synthesis of alkaline terbium tungstates and molybdates by solid-state reaction and their luminescence properties Journal of Japan Society of Colour Material (Shikizai Kyokaishi) 79(12),pp.519-525 (Collaboration) 2006/12
75.	Article	Specific response of osteoblast-like cells on hydroxyapatite layer containing serum protein Journal of Materials Science: Materials in Medicine 17(9),pp.859-867 (Collaboration) 2006/09
76.	Article	Substitution Model of Monovalent (Li, Na, and K), Divalent (Mg), and Trivalent (Al) Metal Ions for Beta-Tricalcium Phosphate Journal of the American Ceramic Society 89(2),pp.688-690 (Collaboration) 2006/02
77.	Article	Chemicovector Effect of Nano-Size-Hydroxyapatite Doped YSZ Ceramics on Apatite Formability in SBF Key Engineering Materials 309-311,pp.526-534 (Collaboration) 2006
78.	Article	Effect of Substitutional Monovalent and Divalent Metal Ions on Mechanical Properties of Beta-Tricalcium Phosphate Journal of the American Ceramic Society 88(8),pp.2315-2318 (Collaboration) 2005/08
79.	Article	Synthesis of bioactive zirconia ceramics on the basis of vector materials science Journal of the Japan Society of Powder and Powder Metallurgy 52(5),pp.347-35 (Collaboration) 2005
80.	Article	Hydroxyapatite-doped zirconia for preparation of biomedical composites ceramics Solid State Ionics 172(1-4),pp.509-513 (Collaboration) 2004/08
81.	Article	Antimicrobial Evaluation and ESR Measurement of Aluminum Anodic Oxide Films Containing an Iodine Compound Proceedings of AESF SUR/FIN 2004-Chicago and INTERFINISH 2004 World Congress pp.775-784 (Collaboration) 2004
82.	Article	EFFECTS OF ELECTRICAL POLARIZATION ON B-TYPE CARBONATED HYDROXYAPATITE Phosphorus Research Bulletin 17,pp.126-129 (Collaboration) 2004
83.	Article	Effect of bone-like layer growth from culture medium on adherence of osteoblast-like cells Biomaterials 24(6),pp.941-947 (Collaboration) 2003/03
84.	Article	Effect of Hydroxyapatite Dopant to Yttria Stabilized Zirconia Ceramics for Biomedical Application Phosphorus Research Bulletin 16,pp.75-82 (Collaboration) 2003
85.	Article	Fabrication of Two-Dimensional SiC/SiC Composites by Hot-Pressing and their Mechanical, Interfacial and Thermal Properties Key Engineering Materials 247,pp.191-194 (Collaboration) 2003
86.	Article	Antimicrobial Characteristics of Anodic Oxidation Coating of Aluminum Impregnated with Iodine Compound Proceedings of The Fourth pacific Rim International Conference on Advanced Materials and Processing pp.1641-1644 (Collaboration) 2002
87.	Article	Antimicrobial Properties and Synthesis of Tricalcium Phosphate Doped with Alkali Metal and Silver Ions Phosphorus Research Bulletin 13,pp.123-126 (Collaboration) 2002
88.	Article	Sintering and Mechanical Properties of Beta-Tricalcium Phosphates Doped with Alkali Metal and Alkali Earth metal Ions Phosphorus Research Bulletin 13,pp.271-274 (Collaboration) 2002
89.	Article	Tribological Properties of Anodic Oxidation Coating of Aluminum Impregnated with Organic Iodine Compound Proceedings of The Fourth pacific Rim International Conference on Advanced Materials and Processing pp.1915-1918 (Collaboration) 2002
90.	Article	Recycling process of fly ash generated from oil burning Materials transactions 42(11),pp.2465-2471 (Collaboration) 2001/11
91.	Article	Modulation of Adherence of Osteoblast-Like Cells by Electrical Polarization of Hydroxyapatite Ceramics Key Engineering Materials, Bioceramics 13 192-195,pp.333-366 (Collaboration) 2001/01
92.	Article	Design for the mechanical properties of esthetic FRP orthodontic wires pp.140 (Collaboration) 2000/09
93.	Article	Preparation of Hydroxyapatite Coatings using R. F. Magnetron Sputtering Journal of Korean Institute of Surface Engineering 32(3),pp.307-311 (Collaboration) 1999/06
94.	Article	Preparation and Sintering of SiC Particulate Dispersed Al₂O₃ Fine Powders by Spray Pyrolysis Method Key Engineering Materials 161-163,pp.407-410 (Collaboration) 1999/01
95.	Article	Preparation of Synthetic Whitlockite by Wet Chemical Method Phosphorus Research Bulletin (6),pp.189-192 (Collaboration) 1996/12
96.	Article	Thermal Behavior of Synthetic Mg-containing Whitlockite Prepared by Wet Chemical Method Phosphorus Research Bulletin 6,pp.349-352 (Collaboration) 1996/12
97.	Article	A High-resolution Electron Microscopy Study of Structural Defects in YBa₂Cu₄O₈ Superconductor Physica C 269,pp.139-148 (Collaboration) 1996/10
98.	Article	Synthesis of Hydroxyapatite by Sol-Gel Method Phosphorus Research Bulletin 5,pp.25-30 (Collaboration) 1995/12
99.	Article	Hydrothermal Synthesis of Copper(II) Phosphate. Phosphorus Research Bulletin 3,pp.19-24 (Collaboration) 1993/12
100.	Article	Syntheses of Tricobalt Orthophosphate Hydrate and Cobalt Hydrogenphosphate. Phosphorus Research Bulletin 1,pp.69-74 (Collaboration) 1991/12
101.	Article	Synthesis and Particle Properteis of Copper(II) Phosphate. Phosphorus Research Bulletin 1,pp.75-80 (Collaboration) 1991/12
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